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Yes. Once the stone is removed, the pain will go away. The stone is likely irritating the urethra and this is what is causing the pain. The doctor should also test the urine for infection to see if you need antibiotics to make the pain go away as well. Hope this helps.
Sounds like the stone is stuck in the urethra. Because you're hurting this bad, I would recommend that you get into the emergency room to have a urologist see you today. They probably need to do cystoscopy to pull the stone out.