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Yes....you should absolutely induce vomiting. Cigarette butts are actually worse for a dog to eat than you'd think because they contain all the residue and carcinogens from smoking the cigarette.
So if you have peroxide on hand, I'd definitely suggest getting her to vomit. The way to make that happen is pretty easy and instructions can be found here:http://www.petplace.com/dogs/how-to-induce-vomiting-emesis-in-dogs/page1.aspx
I would give the peroxide and make her vomit up the butt.