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A legal separation is not the same as a divorce. In fact, the primary difference is that legally separated spouses are not free to remarry. Before you are able to get married legally, your fiance will have to go through the process of getting divorced. She can get divorced in Ohio if she'd lived there for at least 6 months, even if her spouse lives in another country.
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Then she'll need to get a divorce in the United States. Ohio can't issue a marriage license if she has been married before without proof that the prior marriage ended by divorce or death of the spouse.
The best thing you can do is talk to an immigration lawyer about whether she might be able to obtain some other type of visa in order to come over here, establish residency, and file for divorce. That way, you'll be able to get married once the divorce is finalized.