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First, he needs to file a Stay of Removal to prevent him from physically being removed from the U.S. Here is a link:
After that, I would look into 212(h) as a possibility. Here is a link:
If he does not qualify for 212(h), then he has to do something about that conviction so that they do not deport him and he would have the following options to do so:
1) Get a full and unconditional governor's or U.S. Presidential pardon.
2) Hire a VERY good criminal attorney to look into the possibility of reopening his criminal case because something was done incorrectly at the criminal level. If the case can be reopened, then the conviction needs to be vacated (set aside) and then he would need an agreement from the prosecutor not to prosecute him again (which they can do). You can try looking for an attorney at www.ailalawyer.com.
3) Convince the majority of the U.S. Congress to change the law or to make a law of special application only for him called a Private Bill.
These options essentially would eliminate the conviction so that Immigration cannot use it against him to deport him. Unfortunately, sealing or expunging the conviction does not work.
4) IF he became a U.S. Lawful Permanent Resident while inside the U.S. AND he has a U.S. Citizen or U.S. Lawful Permanent Resident spouse or son or daughter that would suffer EXTREME HARDSHIP if he is deported, then he MIGHT stand a chance to not be deported and get Residency again.
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