If the boilers hot water pump any zone pumps are running that chance that there is air trapped in the high points in the system is nearly 100%.
There are air vents near the tops of all radiators, and at other high points in the system, make sure the boiler has at least 15 psig pressure in it, then open each air vent for a few seconds, if any air comes out, before a squirt of water comes out, you have found the problem.
Bleed all of the other air vents in the system, lift the pressure relief handle on the boiler for 1 second then let go, stand clear of its boiling hot water discharge.
then repeat the bleeding process.
Tell me if you have trouble keeping the boiler water pressure up to 15 psig. and if you have in-floor radiant heat.
This is step one, we can go from there until we get the situation resolved.