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It sounds like the substance you have found on your floor is oil out of the freon, this can happen when a freon line ruptures and allows freon to leak out of the system. Check your compressor to see if its running, if so and your refrigerator and freezer are not cool at all this is what has happened, the only way to repair this issue is to repair the leak and have the refrigerator recharged by a professional. Sorry for the bad news, hope this helps.
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