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Are you losing water out of the PRV (the 15mm copper pipe outside about 3ft below the flue)?
Have you managed to look outside?
If it is coming from there then it is easier to fix than a leak on the pipework!
The flue is off the top of the boiler and takes the fumes away.
The PRV is connected to a 15mm copper pipe and goes through the outside wall and may be dripping