UK Immigration Law
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Hi thank you for your question.
As she has permanent residence in the UK which is equivalent to Indefinite Leave to Remain, your divorce will not effect her ability to apply for naturalisation as a British Citizen.
Permanent Residence can be revoked on the basis of Public Policy, Public Health, or Public Security or if the EEA national and/or non-EEA national family member has been away from the UK for more than 2 consecutive years.
I hope this answers your question.