Hi Customer (name blocked for privacy),
As you point out, #1 plays #32. Basically, the best always plays the worst in every round. The second best always plays the 2nd worst, the 16th best, plays the 17th best, etc...
For a VERY thorough explanation, check out the USA Table Tennis (Ping Pong) Tournament Guide here (Chapter 6 is mostly what you want):
http://www.usatt.org/organization/tournaments/tournament_gui de/
Here's what the 64 person NCAA basketball tournament looks like... you can just lop off half of this and voila... 32!
http://www.krtdirect.com/webready/preview.htm?doc=KRT%2Fkrtw ebready%2Fdocs%2F007%2F669
For a nice word document template, go here:
http://www.crowsdarts.com/brackets/tourn.html
This should get you the answer that you're looking for... if not, let me know what else I can do! If this did help, please accept my answer and give me good feedback! Thanks!
Best,
Blueshoes