Within Word you can create new tabs whether it be by left, right or decimal.Can you attach the file you're working on here?
see attached picture
go to home --> paragraph --> drop down menu under line spacing --> line spacing options --> Tabs
From there you can insert tabs based on right left center.. decimal etc.
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I inserted a right alignment tab, should be lined up now.
see attached picture, I circled both locations where it shows the alignment.
The one on the left you can click on to move from right, left center.. etc.
Then you just left click anywhere on the horizontal ruler to place the tab.
To get the tabs to show up. (in picture red circle on left) you have to do the below first.
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