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If you want to manually sort a set of photos then you should create a new album in iPhoto and then drag your pics to it.
You can then choose to sort the album manually.
View the new album you created, then;
Click "View" in the menu bar at the very top of the screen.
Select "Sort Photos"
Then, depending on your version of iPhoto, you can choose to sort by Date or Keyword or Title or Rating or Manually.