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Some email services have a size limit of 10MB, 20MB etc. So even if you compress, you won't be able to send it via email unless the compressed size is smaller than the limit.
To compress the file, right click
or control + click
on the PDF file and select Compress filename
option from the popup menu. Or select the file, click on Finder menu and select Compress filename
. The file will be compressed a put to a ZIP folder in there.If you are still unable to send it via email, then you should try the file sharing websites like www.mediafire.com, www.wikisend.com etc. Just upload the files to those websites and send the link/file ID of the uploaded file to the receiptant and he/she will be able to download it.
Let me know if that didn't work, so we can continue troubleshooting. Don't Rate my answer until you are satisfied.