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Hello. While in Itunes, go to the Itunes menu then Preferences. Select the Advanced tab. Here it will give you the location of your Itunes media. You will need to Copy this folder to your Windows PC. After that, open Itunes on the Windows PC and go to the File menu, then Add Folder to Library and select the folder you copied. It will then import the items into Itunes on the Windows XP computer.