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Hi, I'm Heather, an attorney with 15 years experience, and I can assist for informational purposes.
If he is still married to his ex wife when he married you, then your marriage could be void.
However, it is possible that as a matter of equity, the judge would probably take jurisdiction over the home and other property that was acquired during the time you thought you were married, and divide it in a fair manner.
Here a website that can help you get free and low cost legal aid in Californa: http://www.courts.ca.gov/selfhelp-lowcosthelp.htm
Let me know if that answers your questions?