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The wife can file for divorce on the grounds of adultery, and ask the judge to order temporary custody of the children, temporary child support, temporary spousal support, and sole use and possession of the marital home. There is no waiting period to file for divorce when one spouse is committing adultery. In Pennsylvania, temporary spousal support is usually 40% of the difference between the spouse's incomes. This calculator can help you figure out how much child support you may be entitled to.
If the husband has significant assets or income, the wife can also file a Motion for Attorney's fees, asking that the husband be ordered to pay for her lawyer. Many lawyers will accept the case and file this motion for the client, then taking their money from whatever is recovered from the husband. That may be an option worth exploring, because a lawyer can prepare all of the documents and file them quickly in order to get the money the children need for things like food and clothing.