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You can file divorce against your husband just as you could if he were mentally stable. If he has a guardian, you should serve that person as well. Once the case is filed, you could ask the court to appoint a legal guardian for your husband to ensure that his rights are protected.....this could be a family member or even a lawyer appointed by the court.
Other than possibly adding a person to watch out for your husband's best legal interests, the procedure is basically the same as it would be in any instance.