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If you are legally separtaed then the titled property is yours. You have a options
1) you can call your wife and ask her to return the vehicle.
2)You can file an action for contempt of court since she has violated the court ordered property settlement ( you will need to get the order enforced in the new state),
3) you can file an action for replevin in the state where you wife went to to get possession back.
4) you can simply go to the state and take the car back ( you should get local law enforcement to assist you).
5) you may aslo be able to report the car stolen ( a little drastic since you have chosen to stay married)
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