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Hi and welcome to the site, I’m Louie. Sorry you had to wait awhile but I’ll do my best to help.
Initially, when was the least time you were able to send an email successfully to her?
Are you able to send emails to others with no "Mailer-Daemon" issue?
Appreciate the additional information.
Can you please copy the contents of the Mailer-Daemon message/email to a Notepad or TextEdit/Notes and upload. Click HERE.
Yes please; Copy-n-Paste all the contents of the email sent back to your by Mailer-Daemon.
How do you open/send emails? using Chrome, Firefox, email client/program?
And have you tried to contact your girlfriend by any other means? ...SMS/text, phone call, Skype, IMs?