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Outlook 2016 relies on autodiscover to ensure profile integrity, if your domain doesnt publish autodiscover records, outlook 2016 wont be able to connect.
What you will have to do is create a local xml record following the steps on this page
Scroll down to this section "Create a local Autodiscover.XML File" and follow the steps carefully.. Once you have pasted the file into place in your appdata folder as mentioned, you will then be able to use the autodiscover routine to add your account to outlook 2016.
If you have further questions, or need me to connect and do this for you, let me know.
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