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I see. It's true; some less-than-reputable emails have an 'unsubscribe' link in them that does not do actual unsubscribing.
What syndicate is it?
That site is a dubious matter. If you have enrolled with them, I advise you to disenroll.
Or is it that emails from them are coming to you?
I would advise you that you probably cannot unsubscribe from them. Block their emails instead, using your email system... or mark their emails as Spam. By and by your Spam filter will recognize the emails and sort them into the Spam folder or the Trash folder.