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Photos that are uploaded to iCloud will automatically sync to your Mac.
Make sure that your Mac and iPhone are signed into the same Apple ID account.
On your Mac go into System Preferences then iCloud then Photos then select iCloud Photo Library
On your iPhone, go into Settings then Photos and Camera then select the option for iCloud Photo Library (it should see green)
Once that is complete, your photos will sync automatically through Photos on your Mac computer.
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