What mail program do you use, Is it Windows Mail?
Who do you wish to set up your mail account through?
Let us know
Do you already have an account with Verizon?
If so have you contacted them to add additional email identities?
First you will ned to sign into your Verizon account online https://sso.verizon.net/ssowebapp/VOLPortalLogin?ActualTarget=https://netservices.verizon.net/portal/verizon/protected/afterssologin.jsp?a=b
Once you are in follow this tutorial to setup up to 8 additional email accounts, If you need help there are tutorial movies available here which will show you how to setup your accounts http://netservices.verizon.net/portal/link/help/item?linkflag=verizon_dsl&objId=16744
Let us know if you need more help.