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Hi. My name is***** Thank you for taking care of this girl and helping her to have the care that she needs. It can be a definite challenge to get some caught to take them to the vet. I greatly thank you for wanting to get her to the vet to have her spayed! That will help control the pet population in your area. Honestly, there isn't anything you're going to have that you can safely slip into her food on an at home basis to help catch her. What may be the best thing is to actually get a live trap and place food in it to then have her go in to trap her when she eats. These are a lot of times available at the local animal control offices for local residents to utilize.